{4-Chloro-2-[(2-hydroxyethyl)iminomethyl]phenolato}{4-chloro-2-[(2-oxidoethyl)iminomethyl]phenolato}cobalt(III)

2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide

In the title compound, C(15)H(10)Cl(3)NO(2), an intra-molecular N-H⋯O hydrogen bond forms a six-membered ring and enforces an almost coplanar conformation for the acetamido group, the central benzene ring and the bridging carbonyl C-C(=O)-C group: the dihedral angles between the benzene ring and the acetamide and carbonyl C-C(=O)-C planes are 7.06 (11) and 7.17 (12)°, respectively. The dihedral...

{4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)

In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy-droxy and one oxide O atom from two Schiff base ligands, forming an octa-hedral geometry. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds. The 2-oxidoethyl group is ...

CAS Name: 4-Chloro-2-methylbenzenamine Synonyms: 2-Amino-5-chlorotoluene; 3-chloro-6-aminotoluene; 4-chloro-2- methylaniline; 4-chloro-6-methylaniline; (4-chloro-2-methylphenyl)amine; 4-chloro-2-toluidine; 4-chloro-ortho-toluidine; 5-chloro-2-aminotoluene; para-chloro-ortho-toluidine; 2-methyl-4-chloroaniline; 2-methyl-4- chlorobenzeneamine

Methyl 2-{4-chloro-2-[5-chloro-2-(2-meth­oxy-2-oxoeth­oxy)benz­yl]phen­oxy}acetate

In the crystal structure of the title compound, C(19)H(18)Cl(2)O(6), mol-ecules are connected via weak C-H⋯π inter-actions into closely packed dimers.

2-Chloro-4-iodo­aniline

The title dihaloaniline, C(6)H(5)ClIN, shows no significant hydrogen bonds nor the commonly observed I⋯I inter-actions in the crystal structure, although an amino group and an I atom are available for such contacts. The crystal structure is stabilized by weak inter-actions involving the amine functionality as donor group and N or halogen atoms as acceptors.